| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1302616 | Inorganic Chemistry Communications | 2007 | 4 Pages |
Abstract
Treatments of the MeOH, EtOH and PrOH solutions of 2-acetylpyridine, hydrazine and CuII salts (in molar ratio 2:3:2) afforded respectively the complexes, [CuII(HL)(Cl)](SO3CF3)H2O (1), [CuII(MeL)(H2O)](ClO4)2 (2) and [CuII(EtL)](Cl)](ClO4) (3) (L = bis-(methyl, 2-pyridyl ketone hydrazonyl)methine), in which the ligands, HL, MeL and EtL are formed in situ from oxidative couplings of alcohols and hydrazones.
Graphical abstractProposed transition state of concerted hydrogen transfer from alcohol to [CuII(MPKH-H)2∗]2+Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Jing Xiang, Ye-Gao Yin, Ping Mei, Qin Li,