Article ID Journal Published Year Pages File Type
1302644 Inorganic Chemistry Communications 2011 5 Pages PDF
Abstract

Three Cd(II)-btc coordination polymers exhibiting different networks which are affected by co-ligands such as Acridine (L1), Phenanthridine (L2) and Quinoline (L3): 2-D (4,4) net for [Cd(Hbtc)2(HL1)2] (1), 2-D double-layer for [Cd3(btc)2(L2)2(H2O)2].2H2O (2) and 3-D net for [Cd(btc)(HL3).H2O].2H2O (3).

Graphical abstractCd(II)-btc coordination polymers (H3btc = benzene-1,3,5-tricarboxylic acid) containing different heterocyclic aromatic co-ligands have been isolated under hydrothermal conditions. Each polymer shows different network because the co-ligand might serves as the structure-directing template.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► Three new cadmium coordination polymers based on benzene-1,3,5-tricarboxylic acid. ► Different networks are affected by heterocyclic aromatic co-ligands. ► One polymer is a 2-D (4,4) net. ► One polymer is a 2-D double-layer. ► The third one is a 3-D net.

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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