| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1302704 | Inorganic Chemistry Communications | 2011 | 5 Pages |
Two new porous lanthanide-organic frameworks, {[Ln2(HIDC)3(H2O)2]·7H2O}n [Ln = Tb(1) and Eu(2), H3IDC = imidazole-4,5-dicarboxylic acid], were obtained under hydrothermal conditions. Both of them possess 3D frameworks containing 1D rectangle channels along a-axis. Topological analyses of two complexes reveal that they exhibit unusual 4-nodal (3,4)-connected network. Furthermore, their solid-state luminescent behaviors have been investigated at room temperature.
Graphical AbstractTwo 3D porous lanthanide-organic frameworks containing 1D rectangle channels along a direction feature unusual 4-nodal (3,4)-connected network topology as well as show strong fluorescent emission.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch Highlights► Two 3D porous frameworks constructed by H3IDC ligand and lanthanides ions. ► Frameworks containing 1D rectangle channels. ► Frameworks with novel four-nodal (3,4)-connected network topology.
