| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1302742 | Inorganic Chemistry Communications | 2011 | 4 Pages |
A new 3D lanthanide metal-organic framework with rare flu-3,6-C2/c topology, [Tb(CPEIP)(DMF)(H2O)]·2H2O (1) (DMF = N, N-dimethylformamide), has been synthesized using novel tricarboxylate ligand 5-((4-carboxyphenyl)ethynyl)isophthalic acid (H3CPEIP). It crystallizes in monoclinic space group C2/c. The structure is constructed from metallic 6-connected and organic 3-connected building units with point symbol of (426)2(446287102). The fluorescent properties of compound 1 and organic ligand were studied.
Graphical abstractA new 3D lanthanide metal-organic framework with rare flu-3,6-C2/c topology, [Tb(CPEIP)(DMF)(H2O)]·2H2O (1) (DMF = N, N-dimethylformamide), has been synthesized using novel tricarboxylate ligand 5-((4-carboxyphenyl)ethynyl)isophthalic acid (H3CPEIP). It possesses 3D cross-linked channels.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch Highlights► A new 3D lanthanide MOF has been synthesized using novel tricarboxylate ligand. ► The (3,6)-connected net of compound 1 has been rarely observed in MOFs. ► Compound 1 possesses three dimensional channel system.
