Article ID Journal Published Year Pages File Type
1302779 Inorganic Chemistry Communications 2006 4 Pages PDF
Abstract

A novel end-on azido bridged centrosymmetric heptacoordinated cadmium(II) dimmer [Cd(bpfd)(μ-1,1N3)(N3)]2 · 3H2O (1) (bpfd = N,N′-(bis(pyridin-2-yl)formylidene)ethane-1,2-diamine) has been synthesized and characterized by single-crystal X-ray diffraction. The results show the heteromeric hydrogen-bonded 2D supramolecule that can be exploited to assemble the [Cd(bpfd)(μ-1,1N3)(N3)]2 dimeric building blocks and water of crystallization.

Graphical abstractCentrosymmetric heptacoordinated cadmium(II) dimer [Cd(bpfd)(μ-1,1N3)(N3)]2 · 3H2O (1) (bpfd = N,N′-(bis(pyridin-2-yl)formylidene)ethane-1,2-diamine) has been synthesized and characterized by single-crystal X-ray diffraction.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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