| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1302831 | Inorganic Chemistry Communications | 2006 | 5 Pages |
Abstract
A new polyoxotungstate cluster [W8O19L3(acac)4] (L = −O(CH2)3S(CH2)3O −; acac = acetylacetonate), was synthesized and characterized by single-crystal X-ray diffraction. The structure of the octatungstate cluster exhibits a novel unprecedented polyoxotungstate mode.
Graphical abstractThe reaction of WO2(acac)2 with bis(3-hydroxypropyl)sulfide yields a novel octatungstate-supported molecular cluster [W8O19L3(acac)4] (L = −O (CH2)3S(CH2)3O−; acac = acetylacetonate), which exhibits an unprecedented polyoxotungstate mode. Synthesis, formation of the cluster and its structure are discussed.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![An unprecedented example of polyoxotungstates: Synthesis and characterization of an octatungstate complex [W8O19L3(acac)4] (L = −O(CH2)3S(CH2)3O−)](/preview/png/1302831.png "First Page Preview: An unprecedented example of polyoxotungstates: Synthesis and characterization of an octatungstate complex [W8O19L3(acac)4] (L = −O(CH2)3S(CH2)3O−)")
Authors
Xiaoli Ma, Zhi Yang, Carola Schulzke, Hans-Georg Schmidt, Mathias Noltemeyer,