| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1302916 | Inorganic Chemistry Communications | 2006 | 4 Pages |
Abstract
The reaction of Mn(O2CPh)2 · 2H2O with the sodium salt of phenyl 2-pyridyl ketone oxime and sodium azide in MeOH gives a tetranuclear cage with a [Mn3IIMnIV(μ4-O)(η1,μ2-N3)]7+ core. Magnetic and EPR studies show the cage has an S = 6 ground state.
Graphical abstractThe use of a reaction “blend” containing MnII, PhCO2-, phenyl 2-pyridyl ketone oxime and N3- leads to a new tetranuclear cage featuring the unprecedented [Mn3IIMnIV(μ4-O)(η1,μ2-N3)]7+ core with a 2 e− difference between the manganese oxidation states.Figure optionsDownload full-size imageDownload as PowerPoint slide
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Constantinos J. Milios, Stergios Piligkos, Aidan R. Bell, Rebecca H. Laye, Simon J. Teat, Ramon Vicente, Eric McInnes, Albert Escuer, Spyros P. Perlepes, Richard E.P. Winpenny,