Synthesis, structure and fluorescence properties of a uranyl-2,5-pyridinedicarboxylic acid coordination polymer: The missing member of the UO22+-2,n-pyridinedicarboxylic series

A 3D uranium-pyridinedicarboxylate, compound (1) [UO2(C7H3NO4)], represents the final member of a series of materials incorporating a series of 2,n-pyridinedicarboxylic (pydc) acids (n = 3,4,5,6). The resulting crystal structure [FW = 419.13, monoclinic, P21/n, a = 9.0096(3) Å, b = 8.1371(2) Å, c = 11.6954(4) Å, V = 852.45 Å3, Z = 4] was determined by single crystal X-ray diffraction and fluorescent properties were investigated. Additionally, the complete series of uranium-2,n-pydc materials was examined on a basis of fluorescent behaviors and architectural similarities.

Graphical abstractA 3D uranium-pyridinedicarboxylate, [UO2(C7H3NO4)], was synthesized and represents the final compound in the series of materials incorporating a series of 2,n-pyridinedicarboxylic acids (n = 3,4,5,6). Fluorescent behaviors and architectural comparisons are presented.Figure optionsDownload full-size imageDownload as PowerPoint slide