Organic template-directed indium phosphite-oxalate hybrid material: Synthesis and characterization of a novel 3D |C6H14N2|[In2(HPO3)3(C2O4)] compound with intersecting channels

A novel anionic three-dimensional indium phosphite-oxalate hybrid material, formulated as |C6H14N2|[In2(HPO3)3(C2O4)] (1) was prepared under hydrothermal conditions by using 1,4-diazabicyclo[2.2.2]octane (dabco) as a structure directing agent (SDA). Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in the orthorhombic system space group Pna21 (No. 33) having unit cell parameters a = 12.4143(13) Å, b = 7.7166(8) Å, c = 18.327(2) Å, V = 1755.6(3) Å3, and Z = 4 with R1 = 0.0282, wR2 = 0.0632. The novel 3D open framework is constructed from InO6 octahedra, HPO3 pseudo-tetrahedra and C2O4 units. The assembly of these building units generates intersecting 8- and 12-membered ring (MR) channels along two different directions. To the best of our knowledge, it is the first reported indium phosphite-oxalate hybrid material. Further characterization of compound 1 was performed using X-ray powder diffraction (XRD), infrared (IR) spectra, thermal gravimetric analyses (TGA), inductively coupled plasma (ICP) and elemental analyses.

Graphical abstractA novel three-dimensional indium phosphite-oxalate hybrid material with intersecting 8-MRs and 12-MRs channels has been prepared under hydrothermal conditions by using 1,4-diazabicyclo[2.2.2]octane (dabco) as structure direct agents.Figure optionsDownload full-size imageDownload as PowerPoint slide