| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1303122 | Inorganic Chemistry Communications | 2009 | 4 Pages |
Heterometallic coordination polymers of the form {[SmMn2(imdc)2(OAc)(H2O)]·2H2O}n (1) (H3imdc = 4,5-imidazoledicarboxylic acid, HOAc = acetic acid) were hydrothermally synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction. The results reveal that 1 has a three-dimensional framework containing Sm2Mn4 clusters. The luminescence and magnetic properties of 1 were also investigated.
Graphical abstractThe heterometallic coordination polymers, {[SmMn2(imdc)2(OAc)(H2O)]·2H2O}n (1) (H3imdc = 4,5-imidazoledicarboxylic acid, HOAc = acetic acid), have been hydrothermally synthesized and characterized by elemental analysis, IR, and single crystal X-ray diffraction. X-ray single-crystal structural analyses reveal that 1 is three-dimensional frameworks containing Sm2Mn4 clusters. Furthermore, the luminescent properties and magnetic properties of 1 were investigated.Figure optionsDownload full-size imageDownload as PowerPoint slide
