| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1303196 | Inorganic Chemistry Communications | 2016 | 4 Pages |
•A 3D cobalt-organic framework composed of octahedral cages and trigonal bipyramidal cages was synthesized.•It exhibits notable H2 and CO2 gas adsorption performance.•It shows high adsorption selectivity for CO2 over CH4 and N2.
A cobalt-organic framework (1) consisted of close-packed polyhedral cages is isostructural to CPM-35-Ni. The activated sample (1a) can adsorb high H2 uptake of 88.3 cm3 g− 1 (0.79 wt.%) at 77 K and 1.0 bar. Remarkably, 1a shows high CO2 adsorption capacity and good adsorption selectivity for CO2 over CH4 and N2.
Graphical abstractLarge single crystals of a 3D cobalt-organic framework composed of close-packed polyhedral cages show not only high H2 and CO2 uptakes but also good adsorption selectivity for CO2 over CH4 and N2.Figure optionsDownload full-size imageDownload as PowerPoint slide
