Synthesis, structural characterization and third-order non-linear optical property of new three-dimensional metal-organic polymer [Fe2(μ10-btc)0.5(μ2-ox)0.5(μ2-O)1.5]n

One new metal-organic polymer formulated as [Fe2(μ10-btc)0.5(μ2-ox)0.5(μ2-O)1.5]n1 (btc = 1,2,4,5-benzenetetracarboxylate, pyramellitate; ox = oxalate) has been synthesized by low-temperature solid-state reaction and characterized by single-crystal X-ray diffraction, elemental analyses, TGA, IR spectra and UV–visible spectra. Complex 1 presents the first 3D coordination network structure constructed by bridging btc, ox and O mixed ligands. In 1, carboxyl groups of btc are all deprotonated and they have a new type of μ10-btc coordination mode. The third-order non-linear optical (NLO) properties of the title compound 1 were also investigated and they exhibit the reverse saturable absorption and self-defocusing performance with modulus of the hyperpolarizability (γ) 5.98 × 10−30 esu for 1 in a 7.45 × 10−4 mol dm−3 DMF solution.

Graphical abstractOne new metal–organic polymer formulated as [Fe2(μ10-btc)0.5(μ2-ox)0.5(μ2-O)1.5]n1 (btc = 1,2,4,5-benzenetetracarboxylate, pyramellitate; ox = oxalate) has been synthesized by low-temperature solid-state reaction and characterized by single-crystal X-ray diffraction, elemental analyses, TGA, IR spectra and UV–visible spectra. Complex 1 presents the first 3D coordination network structure constructed by bridging btc, ox and O mixed ligands. In 1, carboxyl groups of btc are all deprotonated and they have a new type of μ10-btc coordination mode. The third-order non-linear optical (NLO) properties of the title compound 1 were also investigated and they exhibit the reverse saturable absorption and self-defocusing performance with modulus of the hyperpolarizability (γ) 5.98 × 10−30 esu for 1 in a 7.45 × 10−4 mol dm−3 DMF solution.Figure optionsDownload full-size imageDownload as PowerPoint slide