Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1303303 | Inorganic Chemistry Communications | 2007 | 4 Pages |
Syntheses are described of two new ligands that contain a central benzene to which are attached via oxygen atoms two pyrazine or quinoxaline rings. These react with copper(I) iodide to form complexes, whose crystal structures reveal coordination polymers consisting of ladders of Cu2I2 rings crosslinked into two-dimensional sheets by the new bridging ligands. The ligands separate the ladders by a distance of ca. 1.6 nm.
Graphical abstractSyntheses are described for two new ligands that contain a central benzene to which are attached via oxygen atoms two pyrazine or quinoxaline rings. These react with copper(I) iodide to form complexes whose crystal structure structures reveal coordination polymers consisting of ladders of Cu2I2 rings crosslinked into two-dimensional sheets by the new bridging ligands. The ligands separate the ladders by a distance of ca. 1.6 nm.Figure optionsDownload full-size imageDownload as PowerPoint slide