Article ID Journal Published Year Pages File Type
1303312 Inorganic Chemistry Communications 2007 5 Pages PDF
Abstract
Two novel organotin(IV) complexes of the types [(Ph3Sn)4(O3POPh)2]n1 and [(Ph3Sn)6(O3POPh)3]22 have been prepared by treatment of phenylphosphoric acid and the Ph3SnCl under different conditions. The complexes 1 and 2 were characterized by elemental analysis, IR and NMR (1H,13C,119Sn) spectroscopy and X-ray crystallography diffraction analysis. The structure analyses reveal that complex 1 is an infinite 1D polymer and complex 2 is a dimer which contains two 24-membered macrocycles.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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