| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1303313 | Inorganic Chemistry Communications | 2007 | 4 Pages |
A new one-dimensional nickel(II) coordination polymer with azido-bridge, [Ni(dpa)(N3)2] · H2O 1 (where dpa is the 2,2′-dipyridylamine ligand) has been synthesized and crystal structure was determined by single-crystal X-ray diffraction. Complex 1 exhibits a zig-zag chain structural arrangement, and the hexa-coordinated Ni(II) ion exhibits a distorted octahedral coordination sphere. The chains topologies are built via three EO and one EE azido bridges. The study of the magnetic properties reveals dominating antiferromagnetic interactions between Ni(II) ions through the EE bridges.
Graphical abstractA novel one-dimensional nickel(II) coordination polymer with azido-bridge, [Ni(dpa)(N3)2] · H2O 1 exhibits a zig-zag chain structural arrangement, which is built via three EO and one EE azido-bridges. The study of the magnetic properties reveals dominating antiferromagnetic interactions between Ni(II) ions through the EE bridges.Figure optionsDownload full-size imageDownload as PowerPoint slide
