| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1303339 | Inorganic Chemistry Communications | 2015 | 4 Pages |
•Two hybrid compounds constructed from Cu-Pyim complexes and {P2Mo5O23}6 − clusters were successfully synthesized.•Synthesis of two compounds shows that pH is crucial for the formation of various structures•The magnetic analyses of two compounds indicate antiferromagnetic interactions between copper ions.
Two inorganic–organic hybrid compounds based on Strandberg-type phosphomolybdates (abbreviated as {P2Mo5O23}6 −) complexes [H3O]2[Cu2(Pyim)2(H2O)3][P2Mo5O23] · 6H2O (1) and [Cu3(Pyim)3(H2O)4][P2Mo5O23] · 7H2O (2) were successfully synthesized at different pH values under hydrothermal conditions. Both 1 and 2 are based on the {P2Mo5O23}6 − clusters connected by copper complexes to generate one dimensional chain. The magnetic analyses of compounds 1 and 2 indicate antiferromagnetic interactions between copper ions.
Graphical abstractTwo inorganic–organic hybrid compounds [H3O]2[Cu2(Pyim)2(H2O)3][P2Mo5O23] · 6H2O (1) and [Cu3(Pyim)3(H2O)4][P2Mo5O23] · 7H2O (2) are based on the {P2Mo5O23}6 - clusters connected by copper complexes to generate one dimensional chains. The magnetic analyses of compounds 1 and 2 indicate antiferromagnetic interactions between copper ions.Figure optionsDownload full-size imageDownload as PowerPoint slide
