| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1303400 | Inorganic Chemistry Communications | 2007 | 4 Pages |
Abstract
In contrast to the ready addition of ligands to nido single-cluster B10H14 the addition of a ligand onto nido: nido double cluster B18H22 needs an oxidizing agent: thus deprotonation of syn-B18H22 followed by treatment with I2 and SMe2 gives [7-(SMe2)-syn-B18H20].
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Macropolyhedral boron-containing cluster chemistry: The reaction of syn-B18H22 with SMe2 and I2 in monoglyme: Structure of [7-(SMe2)-syn-B18H20]](/preview/png/1303400.png "First Page Preview: Macropolyhedral boron-containing cluster chemistry: The reaction of syn-B18H22 with SMe2 and I2 in monoglyme: Structure of [7-(SMe2)-syn-B18H20]")
Authors
TomáÅ¡ JelÃnek, Bohumir Grüner, Ivana CÃsaÅová, Bohumil Å tÃbr, John D. Kennedy,