Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1303412 | Inorganic Chemistry Communications | 2007 | 4 Pages |
Abstract
Two novel 1D polymeric Pb(II) complex containing the Pb2-(μ-N3)2 units, [Pb(phen)(N3)2]n (1) and [Pb(deta)(N3) · (N3)]n (2) (deta and phen are the abbreviations of diethylentriamine and 1,10-phenanthroline, respectively) have been synthesized and characterized by single-crystal X-ray diffraction. Compounds of (1) and (2) are six, PbN6, and five, PbN5, coordinated polymers, respectively. Both of them hold hemidirected coordination geometries. To the best of our knowledge, these 1D coordination polymers are the novel Pb2-(μ-N3)2 units of lead(II) compounds and interact with each other via Ï-Ï stacking and weak Pbâ¯N interactions to create 3D and 2D frameworks.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Farzin Marandi, Babak Mirtamizdoust, Ali Akbar Soudi, Hoong-Kun Fun,