| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1303428 | Inorganic Chemistry Communications | 2007 | 4 Pages |
Abstract
The novel silylated diene 3, a by-product from the reaction of PhSiCl3 with Me3SiCl and lithium in THF at low temperatures was isolated and its structure has been confirmed by X-ray crystallography. The formation of 3 formally arises from a consecutive chemo-reductive cleavage of the aromatic CC double bond in the phenyl-tris(trimethylsilyl)silane (1a) by action of lithium and trimethylchlorosilane.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
C. Krempner, H. Reinke, R. Wustrack,