| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1303471 | Inorganic Chemistry Communications | 2007 | 6 Pages |
Abstract
The reaction of [Pd{PhP(C6H4-2-S)2}(PPh3)] (1) with Ph2CH2CH2Ph2 in dichloromethane affords complex [Pd{PhP(C6H4-2-SCH2Cl) (C6H4-2-S)} (Ph2PCH2CH2PPh2)]Cl (2) as product of the phosphine substitution, the hemilabile properties of the ligand [PhP(C6H4-2-S)2]2â and the CH2Cl2 activation by the de-ligated thiolate moiety.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Synthesis and characterization of [Pd{PhP(C6H4-2-SCH2Cl)(C6H4-2-S)}(Ph2PCH2CH2PPh2)]Cl: An example of hemilability and dichloromethane activation](/preview/png/1303471.png "First Page Preview: Synthesis and characterization of [Pd{PhP(C6H4-2-SCH2Cl)(C6H4-2-S)}(Ph2PCH2CH2PPh2)]Cl: An example of hemilability and dichloromethane activation")
Authors
Valente Gómez-BenÃtez, Rubén A. Toscano, David Morales-Morales,