Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1303486 | Inorganic Chemistry Communications | 2007 | 5 Pages |
Abstract
Thermolysis of [Fe2(CO)6(μ-pdt)] with bis(2-diphenylphosphinoethyl)phenylphosphine (triphos) affords [Fe2(CO)3(μ-pdt){μ,η2-Ph2PCH2CH2P(Ph)CH2CH2PPh2}], the major form of which exists as an interconverting mixture of four isomers at room temperature. Protonation gives a bridging hydride complex in which the fluxionality appears to have been suppressed.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Graeme Hogarth, Idris Richards,