| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1303632 | Inorganic Chemistry Communications | 2006 | 4 Pages |
Abstract
Metallocene complexes with an allyl group (η5-C3H5C5H4)(η5-tBuC5H4)ZrCl2 (2), (η5-C3H5C5H4)(η5-tBuC5H4)ZrCl2 (3) and (η5-C3H5C5H4)(η5-tBu2C5H3)ZrCl2 (4) have been synthesized and characterized. The polymerized metallocene catalyst 5 is prepared by the copolymerization of 3 with styrene in the presence of radical initiator. In the presence of MAO, 2–5 can be used as catalysts for ethylene polymerization with high activities.
Graphical abstractPolymerized catalyst 5 has been synthesized and can be used as catalyst for the polymerization of ethylene in the presence of methylaluminoxane (MAO) as co-catalyst in very high activities.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Jun Zhang, Guo-Xin Jin,