Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1303633 | Inorganic Chemistry Communications | 2006 | 4 Pages |
A novel triazole-bridging polynuclear silver(I) complex, [Ag4(ptr)6](NO3)4 · 4H2O (1), was synthesized with (m-phenol)-1,2,4-triazole (ptr), which is the first discrete tetranuclear complex containing 4-substituted triazoles. The compound features blue fluorescence with a broad emission at 432 nm excited at 363 nm, possibly originating from the π–π∗ transition of the triazole ring.
Graphical abstractThe first discrete tetranuclear complex containing 4-substituted triazole (m-phenol)-1,2,4-triazole (ptr) was obtained from the reaction of AgNO3 with ptr, which shows blue fluorescence feature with a broad emission at 432 nm excited at 363 nm, possibly originating from the π–π∗ transition of the triazole ring.Figure optionsDownload full-size imageDownload as PowerPoint slide