| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1303750 | Inorganic Chemistry Communications | 2006 | 4 Pages |
Abstract
A novel 1,1â²-bisferrocenylimine [{(η5-C5H4)-CHNCy}2Fe] 4 has been synthesized. The double cyclopalladation of 4 with two mole equivalents of Li2PdCl4/NaOAc followed by treatment with tricyclohexylphosphine (PCy3) afforded [PdCl{[(η5-C5H4)-CHO]Fe[(η5-C5H3)-CHNCy]} (PCy3)]6, a monocyclopalladated derivative instead of the expected biscyclopalladated PCy3 adducts. The two new compounds 4 and 6 were characterized by elemental analysis, ESI-MS, IR, 1H NMR and single-crystal X-ray diffraction.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Chen Xu, Jun-Fang Gong, Yan-Hui Zhang, Yu Zhu, Chen-Xia Du, Yang-Jie Wu,