Article ID Journal Published Year Pages File Type
1303771 Inorganic Chemistry Communications 2006 4 Pages PDF
Abstract

The novel diphenylphosphinate bridged coordination polymer catena-[Hg(μ2-O2PPh2)2] was synthesized as a colorless powder from mercury(II) acetate and diphenylphosphinate. Coordinating solvents were used to break the solid-state polymeric chains to allow the crystallization of new polymeric compounds. Crystallization from dimethylsulfoxide/methanol gave the solvent-free polymer catena-[Hg(μ2-O2PPh2)2] while pyridine/methanol gave the 1:2 Hg:pyridine adduct, catena-[Hg(μ2-O2PPh2)2(NC5H5)2]. Both have a polymeric chain with two asymmetrically bridging diphenylphosphinate ligands. The latter also has two pyridine molecules coordinated to the Hg center.

Graphical abstractCoordinating solvents were used to break the solid-state polymeric chains of catena-[Hg(μ2-O2PPh2)2] to allow the crystallization of new polymeric compounds. Crystallization from dimethylsulfoxide/methanol gave the solvent-free polymer catena-[Hg(μ2-O2PPh2)2] while pyridine/methanol gave the 1:2 Hg:pyridine adduct, catena-[Hg(μ2-O2PPh2)2(NC5H5)2].Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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