| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1303790 | Inorganic Chemistry Communications | 2013 | 4 Pages |
Abstract
The kinetic product of the reaction of [(Et2O)2Li{(Ph2P)2CH}] and Me3SiCl, Ph2PCHP(SiMe3)Ph2, was isolated under appropriate conditions and characterized by NMR measurement at 228Â K. Both, reversible P-to-P and irreversible P-to-C migration of the silyl group were observed at higher temperatures and investigated by NMR techniques and quantum chemical calculations.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Jens Langer, Villö K. Pálfi, Björn Schowtka, Helmar Görls, Markus Reiher,