| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1303919 | Inorganic Chemistry Communications | 2012 | 5 Pages |
A novel 3D porous MOF [Cd3(ABTA)2(DMF) (H2O)2] (1) (ABTA = 3, 4′, 5-azobenzenetricarboxylate) has been successfully synthesized by solvothermal reaction of Cd(NO3)24H2O with ABTA. Single-crystal X-ray diffraction result reveals that complex 1 possesses a complicated 3D open framework with two intercrossed 1D channels along [200] and [11–1]. The photoluminescence experimental results of the complex in different solvents indicate that complex 1 has potential application in recognizing small linear conjugated molecule.
Graphical abstractA novel 3D porous MOF [Cd3(ABTA)2(DMF) (H2O)2] (1) (ABTA = 3, 4′, 5-azobenzenetricarboxylate) has been successfully synthesized by solvothermal reaction of Cd(NO3)24H2O with ABTA. Single-crystal X-ray diffraction result reveals that complex 1 possesses a complicated 3D open framework with two intercrossed 1D channels along [200] and [11–1]. The photoluminescence experimental results of the complex in different solvents indicate that complex 1 has potential application in recognizing small linear conjugated molecule.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► A novel MOF based on “Y-type” conjugated ligand has been synthesized. ► Complex 1 features a 3D open framework with an unusual (3,3,6)-connected topology. ► Complex 1 has potential application in recognizing small linear conjugated molecular.
