| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1303942 | Inorganic Chemistry Communications | 2012 | 4 Pages |
A novel two-fold interpenetrating 3D framework consisting of unprecedented tetranuclear Zn(II)-carboxylate units has been synthesized. The tripodal semi-rigid tricarboxylate ligand and 4,4-bipy link the tetranuclear units into a 3,8-connected tfz-d topological network.
Graphical abstractA two-fold interpenetrating 3,8-connected tfz-d topological network consisting of novel tetranuclear Zn(II)-carboxylate units has been synthesized using the tripodal semi-rigid tricarboxylate ligand and 4,4-bipy.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The tripodal semi-rigid tricarboxylate ligand is used for the construction of MOFs. ► The coordination polymer consists of unprecedented tetranuclear Zn(II)-carboxylate units. ► A 3,8-connected tfz-d topology is exhibited.
