A bezoimidazole-based highly selective and low-background fluorescent sensor for Zn2 +

In this article, a new benzoimidazole based Zn2 + fluorescence sensor DABI has been prepared. The sensor displays a rapid and a linear response to Zn2 + with a red-shifted 100-fold turn-on signal from the dark background. The presence of other metal ions especially Cd2 + does not interfere with its Zn2 + response. Molecular modeling study suggests that the Zn2 +-induced red shift of emission and fluorescence turn-on of DABI could be correlated to the coplanation of two aryl planes of 2-aryl substituted benzoimidazole.

Graphical abstractA new benzoimidazole based Zn2 + fluorescence sensor DABI has been prepared and the sensor displays a rapid and a linear response to Zn2 + with a 100-fold turn-on signal from the dark background. The presence of other metal ions especially Cd2 + does not interfere with its Zn2 + response.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► DABI displays a Zn2+-induced 100-fold turn-on signal from the dark background. ► DABI shows high Zn2+ selectivity in CH3CN solution. ► The Zn2+ sensing behavior of DABI was explained well via molecular modeling study.