Synthesis, characterization and crystal structure determination of a new oxovanadium(IV) Schiff base complex: The catalytic activity in the epoxidation of cyclooctene

A new oxovanadium(IV) Schiff base complex, VIVOL2 (1), was prepared by the reaction of a bidentate Schiff base ligand L and VO(acac)2 (L = N-salicylidin-2-chloroethylimine). The Schiff base ligand, L, and its oxovanadium(IV) complex, 1, were characterized by the elemental analysis (CHN) and FT-IR spectroscopy. In addition, 1H-NMR was employed for characterization of the ligand. The crystal structure of 1 was determined by the single crystal X-ray analysis. The Schiff base ligand L acts as a chelating ligand and coordinates via one nitrogen and one oxygen atom to the vanadium center. The complex 1 crystallizes in the monoclinic system, with space group P21/n, having one symmetry-independent V4 + ion coordinating in an approximately square pyramidal N2O3 geometry by two imine nitrogen, two phenolato oxygen atoms from two Schiff base ligands in a square plane and one oxygen atom in an apical position. The catalytic activity of the complex 1 was tested in the epoxidation of cyclooctene. The results showed that the complex 1 was highly active and selective catalyst in optimized conditions in the epoxidation of cyclooctene.

Graphical abstractA new oxovanadium(IV) Schiff base complex, VIVOL2 (1), was prepared and the X-ray analysis showed that the V4+ had an approximately square pyramidal N2O3 geometry. The complex 1 was highly active and selective catalyst in optimized conditions in the epoxidation of cyclooctene.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► A new oxovanadium(IV) Schiff base complex, VIVOL2 (1), was prepared. ► It crystallizes in the monoclinic system having square pyramidal N2O3 geometry. ► Its catalytic activity was tested in the epoxidation of cyclooctene. ► The results showed that it was highly active and selective catalyst.