| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1304205 | Inorganic Chemistry Communications | 2012 | 4 Pages |
Copper(II)-mediated in-situ hydrolyses of 5,5-dimethyl-1-pyrroline N-oxide into 5,5-dimethyl-2-oxo-pyrrolidine-1-olate (L1), and of benzonitrile into benzamide, are observed in the formation of complex [Cu(L1)2(C6H5C(═O)NH2)] (1), which has been characterized by IR, elemental analysis and X-ray diffraction crystallography.
Graphical abstractCopper(II)-mediated in-situ hydrolyses of 5,5-dimethyl-1-pyrroline N-oxide into 5,5-dimethyl-2-oxo-pyrrolidine-1-olate (L1), and of benzonitrile into benzamide, are observed in the formation of complex [Cu(L1)2(C6H5C(═O)NH2)] (1), which has been characterized by IR, elemental analysis and X-ray diffraction crystallography.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Copper(II)-mediated hydrolyses of nitrile and nitrone ► Pyrroline N-oxide hydrolysis to 2-oxo-pyrrolidine-1-olate ► Benzonitrile hydrolysis to benzamide ► Mixed ligand complex formed upon hydrolysis in a one-pot reaction
