Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1304263 | Inorganic Chemistry Communications | 2012 | 4 Pages |
Abstract
Two polyanion clusters [Mo36O108(NO)4(H2O)16]12 − (1) and [Mo36O112(H2O)16Cu0.5(H2O)2]7 − (2) were obtained through ‘one-pot’ reaction at ambient temperature and pressure. Both of 1 and 2 consist of {Mo36} anionic clusters. Interestingly, compound 2 represents a case that the transitional metal copper is anchored into the framework of a giant {Mo36} isopolyanion.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Two polyanion clusters based on {Mo36} isopolyanion. ► Copper is anchored into the framework of a giant {Mo36} isopolyanion. ► Cluster anions are linked to three-dimensional structures by K+ and water molecules.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Zhangang Han, Wenbo Pei, Jingli Xie, Yang Zou, Xiao-Ming Ren,