Article ID Journal Published Year Pages File Type
1304300 Inorganic Chemistry Communications 2010 4 Pages PDF
Abstract

Three new polyoxometalate-based hybrids {[(CH3)3N(CH2)2OH]2(H3O)}[Na2(H2O)6][IMo6O24]·H2O 1 , {Na2[(CH3)3N(CH2)2OH]4}[Al(OH)6Mo6O18]2·8NH2CONH2·4H2O 2 and {Na6(H2O)18[(CH3)3N(CH2)2OH]2(CON2H5)2}[NaMo7O24]2·4NH2CONH2·H2O 3 were successfully synthesized in the choline chloride/urea deep eutectic mixture at room temperature. Reactant quantities of water presents in the nonaqueous eutectic mixture solvent may influence the structure of the products. The three compounds are fully characterized by elemental analyses, IR, UV–vis, TG analyses, power X-ray diffraction and single-crystal X-ray diffraction. The photocatalytic properties of 1 and 2 are investigated.

Graphical abstractThree new polyoxometalate-based hybrids have been synthesized in choline chloride/urea eutectic mixture at room temperature. Reactant quantities of water influence the final structure of the products.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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