Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1304302 | Inorganic Chemistry Communications | 2010 | 4 Pages |
Abstract
Two novel inorganic-organic hybrid compounds (Ni3(Hfcz)4(V3O9)2∙ 2H2O) (1) and Co5(H2O)4(fcz)2(V4O12)2(2) have been successfully constructed, based on [Ni2(V3O9)2]2− “bow tie” clusters and {Co2V2} pure inorganic cages. Structural analysis reveals that the clusters and cages are expanded to a 2D network and 3D framework via NiII and CoII, respectively. In addition, we investigated the optical band gaps of the two compounds: 2.92 eV and 2.23 eV.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Lianjiang Su, Hongying Zang, Hongsheng Liu, Limin Wang, Weihong Li, Zhongmin Su,