| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1304356 | Inorganic Chemistry Communications | 2010 | 4 Pages |
Abstract
A new binuclear mixed-valence complex [ReCl4(py)(μ-O)Re(py)4Cl]·2py was obtained by solvothermal synthesis in a Berghoff autoclave. It has been studied by IR, reflectance spectra, TGA and X-ray measurements, which support the assumption, that two Re centres with different coordination environments are present. Most plausible, yet not unambiguous oxidation state assignment is ReIII/IV.
Graphical abstractA new binuclear mixed-valence complex [ReCl4(py)(μ-O)Re(py)4Cl]·2py with Re centres of different coordination environments was obtained by solvothermal syntheses.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Andrzej Kochel, Małgorzata Hołyńska,