| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1304365 | Inorganic Chemistry Communications | 2010 | 4 Pages |
Abstract
We report the syntheses and single crystal structures of two Fe2(CO)6(μ-ADT) (ADT = azadithiolate) clusters bearing pendant tpy (tpy = 2,2′:6′,2″-terpyridine) domains and containing alkynylthienylene or alkynylphenylene spacers between the Fe-only hydrogenase active site mimic and tpy metal-binding unit.
Graphical abstractSyntheses and single crystal structures of two Fe2(CO)6(μ-ADT) (ADT = azadithiolate) clusters bearing pendant tpy (tpy = 2,2′:6′,2″-terpyridine) domains and containing alkynylthienylene or alkynylphenylene spacers between the Fe-only hydrogenase active site mimic and tpy metal-binding unit are reported.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Edwin C. Constable, Catherine E. Housecroft, Swarna Latha Kokatam, Elaine A. Medlycott, Jennifer A. Zampese,