Article ID Journal Published Year Pages File Type
1304371 Inorganic Chemistry Communications 2010 5 Pages PDF
Abstract

Three novel coordination polymers [(Eu2(Hbidc)2(ox)2·(H2O)3] (1), [Tb2(Hbidc)2(ox)(H2O)2]·4H2O (2), [Er2(Hbidc)2(ox)] (3) have been synthesized with hydrothermal reaction (H3bidc = Benzimidazole-5,6-dicarboxylic acid, H2ox = Oxalic acid) and characterized by elemental analysis, IR and X-ray single crystal diffraction. 1, 2 and 3 have the same crystal system of triclinic, but they exhibit different kinds of metal-organic framework structures. The luminescent properties of 1 and 2 were studied at room temperature.

Graphical abstractThree novel coordination polymers [(Eu2(Hbidc)2(ox)2·(H2O)3] (1), [Tb2(Hbidc)2(ox)(H2O)2]·4H2O (2), [Er2(Hbidc)2(ox)] (3) have been synthesized with hydrothermal reaction (H3bidc = Benzimidazole-5,6-dicarboxylic acid, H2ox = Oxalic acid). X-ray single crystal diffraction reveal 1, 2 and 3 have the same crystal system of triclinic, but they exhibit different kinds of metal-organic framework structures. The luminescent properties of 1 and 2 were studied at room temperature.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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