Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1304410 | Inorganic Chemistry Communications | 2009 | 4 Pages |
Abstract
Bis(1-H-benzo-triazolylmethyl)selenide (L) was synthesized by reacting Se2â generated in situ with 1-(chloromethyl)-1H-benzotriazole. It shows characteristic proton, C-13 and Se-77 NMR spectra. μ-Dichlorobis(η3-allyl)palladium(II) reacts with L resulting in a polymeric complexes which form single crystals of stoichiometry [Pd(η3-C3H5)(L)]·ClO4/PF6·CH3CN (1/2). Their structures are of chain type. The anions ClO4-/PF6- interlink these chains through hydrogen bonds. The 1 and 2 have been found suitable for catalyzing Heck's C-C coupling reactions (TON up to 93,000; conversion up to 93%).
Related Topics
Physical Sciences and Engineering
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Inorganic Chemistry
Authors
Dipanwita Das, Monika Singh, Ajai K. Singh,