Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1304581 | Inorganic Chemistry Communications | 2008 | 4 Pages |
Two new three-dimensional (3D) coordination polymer [Cu2(tetrazolate)3(OH)]n (1) and [Cd2(tetrazolate)3Br]n (2) were synthesized and structurally characterized. By the topology analysis, the complicated architecture of 1 and 2 are all simplified to be the 6-connected pcu-type net. The variable-temperature magnetic susceptibilities (5–300 K) of 1 shows antiferromagnetic interactions of copper(II) ions bridged tetrazolate ligands and/or hydroxide anion.
Graphical abstractTwo new three-dimensional (3D) coordination polymer [Cu2(tetrazolate)3(OH)]n (1) and [Cd2(tetrazolate)3Br]n (2) were synthesized and structurally characterized. By the topology analysis, the complicated architecture of 1 and 2 are all simplified to be the 6-connected pcu-type net.Figure optionsDownload full-size imageDownload as PowerPoint slide