| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1304622 | Inorganic Chemistry Communications | 2008 | 4 Pages |
Abstract
A novel nitrosylrhenium(II) complex salt, [Re(NO)BrL2(PPh3)2](ReO4) (H2L2Â =Â 2-amino-5-(triphenylphosphino)phenol), was prepared from trans-[ReOBr3(PPh3)2] and the rhenium-induced ligand conversion of 2-(benzoxazol-2-yl)benzamine. This is the first example of a complex containing the triphenylphosphonium-amidophenolate ligand L2, formed by the nucleophilic attack of a PPh3 on a coordinated amidophenolate ring.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Irvin Booysen, Thomas I.A. Gerber, Peter Mayer,