| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1304668 | Inorganic Chemistry Communications | 2008 | 4 Pages |
Abstract
A convenient synthesis of the complex [Ir(ppy)2(phC6-acac)] (1, ppy = 2-phenylpyridyl, phC6-acac = 11-(2,5-dibromo-4-hexyloxy-phenoxy)-undecane-2,4-dione) from [{Ir(μ-Cl)(ppy)2}2], phC6-acacH and silver trifluoroacetate as the halide abstractor in refluxing acetone is described. The crystal and molecular structure of 1 was determined by X-ray crystallography.
Graphical abstractThe synthesis and the X-ray crystal structure of the cyclometalated iridium(III) complex [Ir(ppy)2(phC6-acac)] (1, ppy = 2-phenylpyridyl, phc6-acac = 11-(2,5-dibromo-4-hexyloxy-phenoxy)-undecane-2,4-dione) is presented. The emission spectrum of 1 exhibits this complex as a green-light-emitting compound.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Marion Graf, Valeria Gancheva, Manuel Thesen, Hartmut Krüger, Peter Mayer, Karlheinz Sünkel,