Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1304675 | Inorganic Chemistry Communications | 2008 | 5 Pages |
Abstract
Three manganese coordination polymers [Mn(mbtz)2(dca)2(H2O)]n (1), [Mn(mbtz)2Cl2]n (2) and [Mn(mbtz)2(NCS)2]n (3) have been synthesized and characterized. There are two kinds of mbtz ligands in 1. One acts as bridging (bidentate) coordination mode. The other shows terminal (monodentate) coordination mode. The bridging mbtz ligands link the Mn(II) atoms to form the one-dimensional helical chain in 1, 2 and 3 are similar one-dimensional chain containing double bridges of mbtz ligand. 1, 2 and 3 all exhibit blue luminescent emissions maximum in the solid state at room temperature.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Haiyan Ge, Kui Liu, Yuan Yang, Baolong Li, Yong Zhang,