Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1304712 | Inorganic Chemistry Communications | 2008 | 4 Pages |
A 3d–4f heterometallic coordination polymer, {[Cu10Er4(IN)14ClBr7(H2O)10] · 2H2O}n (1) [IN = isonicotinate], has been synthesized by hydrothermal reaction of the ligand with CuBr2, NaCl and Er2O3. Complex 1 represents a rare 3D heterometallic coordination framework constructed from Er-carboxylate subunits and unique Cu-halide (Br/Cl) chains that are bridged by a single type of linear ligand. Furthermore, the luminescent properties of complex 1 have also been investigated.
Graphical abstractA 3D 3d–4f coordination polymer, {[Cu10Er4(IN)14ClBr7(H2O)10] · 2H2O}n (1) [IN = isonicotinic acid], has been hydrothermal synthesized and characterized. Complex 1 shows a rare 3D heterometallic coordination framework. Furthermore, the luminescent properties of complex 1 have also been investigated.Figure optionsDownload full-size imageDownload as PowerPoint slide