| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1304749 | Inorganic Chemistry Communications | 2008 | 4 Pages |
The synthesis, spectroscopic and structural characterization of the carbene ligand precursor bis(4-benzyl-1,2,4-triazol-4-ium-1-yl)dihydroborate has been described. Treatment with Ag2O leads to the silver(I) complex of the new monoanionic bis(4-benzyl-1,2,4-triazol-5-ylidene-1-yl)dihydroborate dicarbene ligand. The resulting dimetallacycle carbene complex has been used to synthesize the homoleptic gold(I) complex by transmetallation reaction.
Graphical abstractThe synthesis, spectroscopic and structural characterization of the carbene ligand precursor bis(4-benzyl-1,2,4-triazol-4-ium-1-yl)dihydroborate has been described. Treatment with Ag2O leads to the silver(I) complex of the new monoanionic bis(4-benzyl-1,2,4-triazol-5-ylidene-1-yl)dihydroborate dicarbene ligand. The resulting dimetallacycle carbene complex has been used to synthesize the homoleptic gold(I) complex by transmetallation reaction.Figure optionsDownload full-size imageDownload as PowerPoint slide
