A novel chiral 3D supramolecular framework based on organooxotin cluster

A novel triorganotin compound, namely [(Ph3Sn)3(CO3)(EtOH)3] · (ntb) · Cl · H2O (1), exhibits the novel chiral 3D supramolecular structure with a (10, 3) topology based on the organooxotin cluster, in which ntb ligand and [(Ph3Sn)3(CO3)(EtOH)3]+ unit act as three-connected nodes and link each other through O–H⋯N bonds.

Graphical abstractA novel triorganotin compound, namely [(Ph3Sn)3(CO3)(EtOH)3] · (ntb) · Cl · H2O, exhibits the novel chiral 3D supramolecular structure with a (10, 3) topology based on the organooxotin cluster, in which ntb ligand and [(Ph3Sn)3(CO3)(EtOH)3]+ unit act as three-connected nodes and link each other through O–H⋯N bonds.Figure optionsDownload full-size imageDownload as PowerPoint slide