Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1304809 | Inorganic Chemistry Communications | 2008 | 4 Pages |
With the amorphous Pt-MeO-salen solid (MeO-salen = N,N′-bis(3-methoxy-salicylidene)-ethylene-1,2-diamine) as the precursor, a new 1D polymeric complex [K2(Pt-MeO-salen)2Ni(CN)4]n · 0.5nEt2O (1) has been characterized. The luminescent property of the complex shows that the 1D helical stacking of well-defined Pt-MeO-salen monomers has modulated the energy order of the excited state in solid state at different temperatures.
Graphical abstractWith the amorphous Pt-MeO-salen solid (MeO-salen = N,N′-bis(3-methoxy-salicylidene)-ethylene-1,2-diamine) as the precursor, a new 1D polymeric complex [K2(Pt-MeO-salen)2Ni(CN)4]n · 0.5nEt2O (1) has been characterized. The luminescent property of the complex shows that the 1D helical stacking of well-defined Pt-MeO-salen monomers has modulated the energy order of the excited state in solid state at different temperatures.Figure optionsDownload full-size imageDownload as PowerPoint slide