Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1304810 | Inorganic Chemistry Communications | 2008 | 4 Pages |
Abstract
Two new complexes, [Cu(L)2(CH3COO)2(H2O)] · 6H2O (1) and [Cu2(L)2(CH3COO)4] · 2C2H5OH (2) (where LN-(4-chlorophenyl)-3-pyridinecarboxamide), have been synthesized. Solvents control the coordination mode to form different supramolecular assemblies. Complexes 1 and 2 represent 3D and 2D networks, respectively. Interestingly, two scarcely reported cyclic water tetramers with C2h and D2h symmetries simultaneously populated in the channels of 1 have been observed.
Related Topics
Physical Sciences and Engineering
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Inorganic Chemistry
Authors
Chun-Yue Shi, Chun-Hua Ge, En-Jun Gao, Hong-Xi Yin, Qi-Tao Liu,