Article ID Journal Published Year Pages File Type
1304901 Inorganic Chemistry Communications 2007 4 Pages PDF
Abstract

As a colorimetric anion sensor, the non-covalent charge-transfer complex, formed by di(hydroxymethyl)-di-(2-pyrrolyl) methane 1 and TCNQ 2, may be used for higher sensitive and selective detection of SO32- than other inorganic anions in a neutral buffered aqueous system. The excellent system properties is hopeful to be used in the monitoring fields of food products and environmental pollutant.

Graphical abstractThe colorimetric sensor based on the charge-transfer complex showed high sensitivity for SO32- in a neutral buffered water/organic solvent system. The experiments confirmed that the color change of the dipyrromethane-TCNQ complex solution in the presence of SO32- is ascribed to the competitive binding of SO32- to TCNQ subunit and is proved to be a reversible procedure.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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