A novel 3D double helix cobalt(II) coordination polymer: Synthesis, crystal structures and third-order non-linear optical properties

One new metal-organic complex formulated as {[Co(bipy)3][Co2(μ2–ox)3]}n1 (bipy = 2,2′-bipyridyl; ox = oxalate) has been synthesized by low-temperature solid-state reaction and characterized by single-crystal X-ray diffraction, elemental analyses, IR spectra and UV–visible spectra. The complex 1 contains helical chains composed of left-handed and right-handed helices interlaced in pairs. The third-order non-linear optical (NLO) properties of the 1 were also investigated and they exhibit the reverse saturable absorption and self-defocusing performance with modulus of the hyperpolarizability (γ) 5.75 × 10−30 esu for 1 in a 2.36 × 10−4 mol dm−3 DMF solution.

Graphical abstractOne new metal-organic complex formulated as {[Co(bipy)3][Co2(μ2–ox)3]}n1 (bipy = 2,2′-bipyridyl; ox = oxalate) has been synthesized by low-temperature solid-state reaction and characterized by single-crystal X-ray diffraction, elemental analyses, IR spectra and UV–visible spectra. The complex 1 contains helical chains composed of left-handed and right-handed helices interlaced in pairs. The third-order non-linear optical (NLO) properties of the 1 were also investigated and they exhibit the reverse saturable absorption and self-defocusing performance with modulus of the hyperpolarizability (γ) 5.75 × 10−30 esu for 1 in a 2.36 × 10−4 mol dm−3 DMF solution.Figure optionsDownload full-size imageDownload as PowerPoint slide