| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1304961 | Inorganic Chemistry Communications | 2007 | 4 Pages |
A complex Cu[(PPh3)2O](acac)[(PPh3)2O = Bis(2-diphenyl-phosphinophenyl) ether; acac = acetylacetone] was obtained by solution reactions and structurally characterized. The title complex is characterized by an isolated structure. X-ray structure analysis of the title complex shows that acac and (PPh3)2O behave as chelating ligands. Photoluminescent investigation reveals that the title complex displays a strong blue-light emission.
Graphical abstractA complex that is the first example in which the Cu+ center being charge-compensated by a coordinating acac− anion, was obtained by solution reactions and structurally characterized. X-ray structure analysis shows that acac and (PPh3)2O behave as chelating ligands. Photoluminescent investigation reveals that the title complex displays a strong blue-light emission.Figure optionsDownload full-size imageDownload as PowerPoint slide
: Cu+ charge-compensated by a coordinating acac− anion](/preview/png/1304961.png "First Page Preview: Cu[(PPh3)2O](acac): Cu+ charge-compensated by a coordinating acac− anion")